Electrosynthesis of polyindole-carboxylic acids on stainless steel and their corrosion protection at different temperatures in acidic solution
| Primer Autor |
Ramirez, A. M. R.
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| Co-autores |
Mieres, Alba Florencia.
Pineda, F.
Grez, P.
Heyser, Cristopher.
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| Título |
Electrosynthesis of polyindole-carboxylic acids on stainless steel and their corrosion protection at different temperatures in acidic solution
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| Editorial |
ELSEVIER SCIENCE SA
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| Revista |
PROGRESS IN ORGANIC COATINGS
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| Lenguaje |
en
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| Resumen |
Poly (indole-5-carboxylic acid) (5-PICA), Poly (indole-6-carboxylic acid) (6-PICA), and Poly (indole-7-carboxylic acid) (7-PICA) were electrowinning onto AISI304 stainless steel by cyclic voltammetry. They were characterized structurally and morphologically by IR spectroscopy and scanning electron microscopy (SEM). In addition, the study about corrosion protection was carried out using linear scanning voltammetry (LSV) and electrochemical impedance spectroscopy (EIS) in 0.5 mol.L-1 H2SO4 at temperatures of 20 degrees C and 45 degrees C. The results showed a close relationship between the morphology of the polymer and the carboxylic group (-COOH) position, which also presented a spatial arrangement according to its branching. Furthermore, it directly modified its hydrophobicity, influencing the anticorrosive protection of AISI304 stainless steel. It provides a corrosion potential between 0.198 and 0.402 V, which is more positive than unprotected steel. Finally, the study revealed better protection at low temperatures, decreasing at 45 degrees C.
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| Tipo de Recurso |
artículo original
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| Description |
The authors acknowledge the financial support of ANID-Chile through Fondecyt, grant number Project No 11190995.
Los autores agradecen el apoyo financiero de ANID-Chile a través de Fondecyt, subsidio número Proyecto No 11190995.
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| doi |
10.1016/j.porgcoat.2022.107075
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| Formato Recurso |
PDF
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| Palabras Claves |
Corrosion
AISI304
Poly (indole-5-carboxylic acid)
Poly (indole-6-carboxylic acid)
Poly (indole-7-carboxylic acid)
INDOLE-5-CARBOXYLIC ACID
CONDUCTING POLYMERS
MILD-STEEL
POLY(INDOLE-5-CARBOXYLIC ACID)
ELECTROCHEMICAL SYNTHESIS
COATINGS
304-STAINLESS-STEEL
PERFORMANCE
ELECTRODEPOSITION
POLYMERIZATION
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| Ubicación del archivo | |
| Categoría OCDE |
Química Aplicada
Ciencia de Materiales
Recubrimientos y Películas
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| Materias |
Corrosión
AISI304
Poli (ácido indol-5-carboxílico)
Poli (ácido indol-6-carboxílico)
Poli (ácido indol-7-carboxílico)
ÁCIDO INDOL-5-CARBOXÍLICO
POLÍMEROS CONDUCTORES
ACERO SUAVE
POLY( ÁCIDO INDOL-5-CARBOXÍLICO)
SÍNTESIS ELECTROQUÍMICA
RECUBIERTOS
ACERO INOXIDABLE 304
RENDIMIENTO
ELECTRODEPOSICIÓN
POLIMERIZACIÓN
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| Título de la cita (Recomendado-único) |
Electrosynthesis of polyindole-carboxylic acids on stainless steel and their corrosion protection at different temperatures in acidic solution
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| Identificador del recurso (Mandatado-único) |
artículo original
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| Versión del recurso (Recomendado-único) |
version publicada
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| Condición de la licencia (Recomendado-repetible) |
0
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| Derechos de acceso |
embargado
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| Access Rights |
embargado
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| Referencia del Financiador (Mandatado si es aplicable-repetible) |
ANID-FONDECYT 11190995
ANID FONDECYT 11190995
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| Id de Web of Science |
WOS:000888930700002
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cienciaabierta.ufro.cl
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