Evaluation of a miniaturized portable NIR spectrometer for the prediction of soil properties in Mediterranean central Chile

Primer Autor
Salazar, Osvaldo
Co-autores
Benvenuto, Angelo
Fajardo, Mario
Fuentes, Juan Pablo
Najera, Francisco
Celedon, Ayleen
Pfeiffer, Marco
Renwick, Leah L. R.
Seguel, Oscar
Tapia, Yasna
Casanova, Manuel
Título
Evaluation of a miniaturized portable NIR spectrometer for the prediction of soil properties in Mediterranean central Chile
Editorial
ELSEVIER
Revista
GEODERMA REGIONAL
Lenguaje
en
Resumen
Near-infrared (NIR) spectrometry to estimate soil properties has been evolving toward more portable and accessible equipment in recent years for the prediction of indicators of soil fertility in agroecosystems. There were two objectives of this study. First, to calibrate and validate a miniaturized portable NIR spectrometer NeoSpectra-Module 2.5 with a limited spectral range (1350-2500 nm) for the prediction of total nitrogen (TN), soil organic carbon (SOC), soil pH, clay content and exchangeable cations (Ca2+, Mg2+, K+ and Na+) in dry conditions. And second, to evaluate the use of an external orthogonalization parameter (EPO) to reduce the effect of soil moisture in samples with field moisture conditions collected from Mediterranean central Chile (33 SL to 36 SL). Soil classified as Mollisols, Alfisols and Inceptisols was sampled (n = 170) from 0 to 30 cm depth and scanned with the NeoSpectra spectrometer. The spectrometer showed good performance (R2 > 0.5 and/or RPIQ>1.4) for predictions of SOC and exchangeable cations. When the spectra data without transformation was used (raw spectra) versus transformed spectra, better performance in the predictions was obtained for TN, SOC, pH, clay content and Ca2+. The cubist model (CM) showed better performance than partial least squares (PLSR) for most assessed soil properties. The EPO procedure allowed us to decrease the error due to soil moisture in the prediction of some soil properties. Although the use of a miniaturized portable NIR spectrometer showed promising results for prediction of soil properties, future testing should increase the number of soil samples, vary the spectral data processing, and/or test new miniaturized portable NIR spectrometers with a wider spectral range.
Fecha Publicación
2023
Tipo de Recurso
artículo original
doi
10.1016/j.geodrs.2023.e00675
Formato Recurso
PDF
Palabras Claves
External parameter orthogonalization
Hyperspectral image
Partial least squares
Conditional regression trees
Pedometrics
Near-infrared spectroscopy
Mollisols
Alfisols
Inceptisols
Ubicación del archivo
Categoría OCDE
Agricultura
Materias
Ortogonalización de parámetros externos
Imagen hiperespectral
Mínimos cuadrados parciales
Árboles de regresión condicional
Pedometría
Espectroscopia de infrarrojo cercano
Molisoles
Alfisoles
Inceptisoles
Identificador del recurso (Mandatado-único)
artículo original
Versión del recurso (Recomendado-único)
versión publicada
Derechos de acceso
metadata
Access Rights
metadata
Id de Web of Science
WOS:001059492800001
ISSN
2352-0094
Categoría WOS
Agricultura
Referencia del Financiador (Mandatado si es aplicable-repetible)
ANID-FONDECYT 1201497
ANID-FONDECYT 3210036
ANID-FONDEQUIP EQM160084
ANID FONDECYT 1201497
ANID FONDECYT 3210036
ANID FONDEQUIP EQM160084
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