Evaluating natural and anthropogenic inputs on the distribution of potentially toxic elements in urban soil of Valdivia, Chile

Primer Autor
Vera, Francisca
Co-autores
Tardani, Daniele
Alvarez-Amado, Fernanda
Tolorza, Violeta
Lacassie, Juan Pablo
Jullian, Domingo
Sepulveda, Carolina
Sanchez-Alfaro, Pablo
Daniele, Linda
Gutierrez, Leopoldo
Título
Evaluating natural and anthropogenic inputs on the distribution of potentially toxic elements in urban soil of Valdivia, Chile
Editorial
SPRINGER
Revista
ENVIRONMENTAL GEOCHEMISTRY AND HEALTH
Lenguaje
en
Resumen
The increasing population in urban areas in the last decades requires an effort to understand the geochemistry of contaminant elements in urban soil. Topsoil plays a crucial role in the exposure of Potentially Toxic Elements (PTEs) to humans through ingestion, dermal contact, and inhalation. In Chile, the last census revealed that 88.6% of people live in cities or towns and only 11.4% in rural areas. This study presents the first systematic geochemical survey of urban soil in the city of Valdivia, in the South of Chile. Topsoil samples (0-10 cm depth) were collected in less disturbed locations within the city at 130 sampling sites using a grid of 0.25 km(2) squares covering a total area of approximately 30 km(2). The concentrations of Al, Fe, Na, Ca, Mg, K, Ti, Be, V, Cr, Mn, Co, Ni, Cu, Zn, As, Mo, Sn, Cd, Se, Pb and Hg were measured. The results showed that high concentrations of Cu, V, Zn and Pb are located mainly in the city's northern area and exceed international soil quality legislation for agricultural use. Data processing comprised plotting of individual spatial distribution maps and the use of a combination of multivariate statistical methods. Hierarchical cluster analysis and principal component analysis identified three element associations. The two element groups V-Al-Ti-Fe-Cr-Co-Mn-Be-Ni and Ca-Na-K-As-Mg are interpreted as a dominant lithological origin related to the most pristine soil conditions in less populated areas. By contrast, the Sn-Pb-Zn-Mo-(Cu-Hg) association presents a significant correlation with urbanization indicators, including vehicular traffic and industrial activities developed since the end of the nineteenth century in Valdivia.
Fecha Publicación
2023
Tipo de Recurso
artículo original
doi
10.1007/s10653-023-01687-5
Formato Recurso
PDF
Palabras Claves
Quality control
Cluster analysis
Principal components
Factor scores maps
Health risk assessment
Vehicular traffic
Ubicación del archivo
Categoría OCDE
Ingeniería
Ciencias Ambientales y Ecología
Salud Pública, Ambiental y Ocupacional
Recursos Hídricos
Materias
Control de calidad
Análisis de conglomerados
Componentes principales
Mapas de puntuaciones factoriales
Evaluación de riesgos para la salud
Tráfico de vehículos
Página de inicio (Recomendado-único)
7841.0
Página final (Recomendado-único)
7859
Identificador del recurso (Mandatado-único)
artículo original
Versión del recurso (Recomendado-único)
versión publicada
Derechos de acceso
acceso abierto
Access Rights
acceso abierto
Id de Web of Science
WOS:001035499700001
ISSN
0269-4042
Tipo de ruta
verde# hibrida
Categoría WOS
Ingeniería
Ciencias Ambientales y Ecología
Salud Pública, Ambiental y Ocupacional
Recursos Hídricos
Referencia del Financiador (Mandatado si es aplicable-repetible)
ANID-FONDECYT 1201219
ANID-FONDECYT 11220777
ANID-FONDECYT 11190864
ANID-FONDAP 15130015
UFRO VRIP20P001
ANID FONDECYT 1201219
ANID FONDECYT 11220777
ANID FONDECYT 11190864
ANID FONDAP 15130015
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