Impact of cooling rate and shear flow on crystallization and mechanical properties of wax-crystal networks
| Primer Autor |
Marangoni, Alejandro G.
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| Co-autores |
Werner-Carcamo, Erwin R.
Rubilar, Monica
Macias-Rodriguez, Braulio A.
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| Título |
Impact of cooling rate and shear flow on crystallization and mechanical properties of wax-crystal networks
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| Editorial |
AIP Publishing
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| Revista |
PHYSICS OF FLUIDS
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| Lenguaje |
en
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| Resumen |
Wax oleogels are one of the most promising strategies to produce trans-fat free and low-saturate functional fats. Under quiescent isothermal conditions, waxes form strong space-filling networks where oil is embedded. Nevertheless, in industrial processes, crystallization conditions deviate significantly from being isothermal and quiescent, yet these far from equilibrium conditions have received limited attention in the literature. Cooling and shear rate gradients during crystallization can promote molecular alignment, crystal growth, and crystal network reorganization that hold the potential to tune the mechanical properties of oleogels. Therefore, this study aimed to investigate the impact of different controlled cooling and shear rates during the crystallization process of beeswax oleogels. An analysis of both small and large amplitude oscillatory shear was conducted to understand the linear and nonlinear mechanical properties of oleogels. Additionally, microscopic/macroscopic analyses, including oil-binding capacity, were performed. The results indicate that sheared oleogels display plastic-like behavior, lower linear elastic moduli, and a higher perfect plastic dissipation ratio than oleogels cooled under quiescent conditions, which displayed stiff, brittle-like characteristics. In addition, these oleogels displayed a microstructure with smaller crystals than oleogels cooled under quiescent conditions. This phenomenon can be attributed to a transition of oleogels from a strong, yet brittle interconnected particle network, to a dispersion of jammed crystal particles that align more easily along the direction of flow, resulting in minimal additional contribution from viscous stress after yielding. Therefore, a controlled cooling and shear rate application is an effective method to tune the mechanical properties of wax oleogels.
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| Fecha Publicación |
2023
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| Tipo de Recurso |
artículo original
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| Description |
Los autores agradecen el apoyo financiero de la Universidad de La Frontera a través de la Beca para promover la Internacionalización (Proyecto FRO1999), el Proyecto Fondecyt de la Agencia Nacional de Investigación y Desarrollo de Chile (ANID, N grados 1200942), y el Consejo de Investigaciones en Ciencias Naturales e Ingeniería de Canadá, Beca No. RGPIN2020-04983. Se agradece la asistencia técnica de Nicole Shaw con mediciones de reología y microscopía.
|
| doi |
10.1063/5.0162427
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| Formato Recurso |
PDF
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| Ubicación del archivo | |
| Categoría OCDE |
Mechanics
Physics, Fluids & Plasmas
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| Disciplinas de la OCDE |
Ingeniería de los Materiales
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| Id de Web of Science |
WOS:001078492700008
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| Referencia del Financiador (Mandatado si es aplicable-repetible) |
UFRO FRO1999
ANID 1200942
Natural Sciences and Engineering Research Council of Canada RGPIN2020-04983
|
| Título de la cita (Recomendado-único) |
Impact of cooling rate and shear flow on crystallization and mechanical properties of wax-crystal networks
|
| Identificador del recurso (Mandatado-único) |
artículo original
|
| Versión del recurso (Recomendado-único) |
versión publicada
|
| Editorial |
AIP Publishing
|
| Revista/Libro |
PHYSICS OF FLUIDS
|
| Categoría WOS |
Mecánica
Física, Fluidos y Plasmas
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| Idioma |
en
|
| ISSN |
1089-7666
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| Derechos de acceso |
metadata
|
| Access Rights |
metadata
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